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Prefered Brands of HCL and Phosphoric Acid
- mg2
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24 Aug 2025 16:02 #87332
by mg2
Prefered Brands of HCL and Phosphoric Acid was created by mg2
You might find the following conversion of 5% HCl to a pH value (according to Grok... AI):
### Conversion of 5% HCl to pH
To convert a 5% (w/w) HCl solution to its pH value, follow these steps. Note that HCl is a strong acid, so it fully dissociates, and pH is calculated as -log₁₀[H⁺], where [H⁺] equals the molarity of the solution.
1. **Identify the concentration and properties**:
5% HCl means 5 grams of HCl per 100 grams of solution. The molar mass of HCl is 36.46 g/mol. The density of a 5% aqueous HCl solution is approximately 1.0228 g/cm³ (at ~20°C).
2. **Calculate the molarity (M)**:
Use the formula for molarity from weight percent:
M = (weight percent × density × 10) / molar mass
M = (5 × 1.0228 × 10) / 36.46
= 51.14 / 36.46
≈ 1.403 M
This means [H⁺] = 1.403 mol/L.
3. **Calculate the pH**:
pH = -log₁₀(1.403)
First, compute log₁₀(1.403):
log₁₀(1.4) ≈ 0.1461
Adjust for 1.403: log₁₀(1.403) ≈ 0.1461 + (0.003 / 1.4) × 0.4343 ≈ 0.1461 + 0.00093 ≈ 0.147
Thus, pH ≈ -0.147
(Note: pH values can be negative for concentrated strong acid solutions, as [H⁺] > 1 M.)
### Table of HCl Concentrations from 1% to 10% (w/w) and Corresponding pH Values
The table below uses the same calculation method for each percentage, with densities sourced from a density-concentration table for aqueous HCl solutions. Densities (in g/cm³ at ~20°C) are: 1.0031 (1%), 1.0081 (2%), 1.0130 (3%), 1.0179 (4%), 1.0228 (5%), 1.0278 (6%), 1.0327 (7%), 1.0377 (8%), 1.0426 (9%), 1.0476 (10%). Molarities are calculated as above, and pH = -log₁₀(M), rounded to three decimal places.
| % HCl (w/w) | pH |
|
|
|
| 1% | 0.560 |
| 2% | 0.257 |
| 3% | 0.079 |
| 4% | -0.048 |
| 5% | -0.147 |
| 6% | -0.228 |
| 7% | -0.297 |
| 8% | -0.357 |
| 9% | -0.411 |
| 10% | -0.458 |
### Conversion of 5% HCl to pH
To convert a 5% (w/w) HCl solution to its pH value, follow these steps. Note that HCl is a strong acid, so it fully dissociates, and pH is calculated as -log₁₀[H⁺], where [H⁺] equals the molarity of the solution.
1. **Identify the concentration and properties**:
5% HCl means 5 grams of HCl per 100 grams of solution. The molar mass of HCl is 36.46 g/mol. The density of a 5% aqueous HCl solution is approximately 1.0228 g/cm³ (at ~20°C).
2. **Calculate the molarity (M)**:
Use the formula for molarity from weight percent:
M = (weight percent × density × 10) / molar mass
M = (5 × 1.0228 × 10) / 36.46
= 51.14 / 36.46
≈ 1.403 M
This means [H⁺] = 1.403 mol/L.
3. **Calculate the pH**:
pH = -log₁₀(1.403)
First, compute log₁₀(1.403):
log₁₀(1.4) ≈ 0.1461
Adjust for 1.403: log₁₀(1.403) ≈ 0.1461 + (0.003 / 1.4) × 0.4343 ≈ 0.1461 + 0.00093 ≈ 0.147
Thus, pH ≈ -0.147
(Note: pH values can be negative for concentrated strong acid solutions, as [H⁺] > 1 M.)
### Table of HCl Concentrations from 1% to 10% (w/w) and Corresponding pH Values
The table below uses the same calculation method for each percentage, with densities sourced from a density-concentration table for aqueous HCl solutions. Densities (in g/cm³ at ~20°C) are: 1.0031 (1%), 1.0081 (2%), 1.0130 (3%), 1.0179 (4%), 1.0228 (5%), 1.0278 (6%), 1.0327 (7%), 1.0377 (8%), 1.0426 (9%), 1.0476 (10%). Molarities are calculated as above, and pH = -log₁₀(M), rounded to three decimal places.
| % HCl (w/w) | pH |
|
|
|
| 1% | 0.560 |
| 2% | 0.257 |
| 3% | 0.079 |
| 4% | -0.048 |
| 5% | -0.147 |
| 6% | -0.228 |
| 7% | -0.297 |
| 8% | -0.357 |
| 9% | -0.411 |
| 10% | -0.458 |
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- CLO2
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25 Aug 2025 02:13 - 25 Aug 2025 02:18 #87335
by CLO2
Replied by CLO2 on topic Prefered Brands of HCL and Phosphoric Acid
The following is from AI bot Leo on Brave Search:
HCl to pH Conversion
"The pH of a 5% hydrochloric acid (HCl) solution cannot be directly calculated from the percentage concentration without knowing the specific density of the solution to convert it to molarity. However, the pH of a 5 M HCl solution, which is a common reference point for concentrated HCl, is approximately -0.69 when calculated using the standard formula \mathrm{pH} = -\log[\ce{H3O+}], assuming complete dissociation of the strong acid. This calculation assumes the concentration of hydronium ions [\ce{H3O+}] is equal to the molar concentration of HCl.
It is important to note that for such a high concentration, the actual pH is influenced by the activity of the ions rather than just their concentration, and the true pH is likely lower than -0.69 due to non-ideal behavior. For a 5 M HCl solution, the pH is estimated to be around -1.1 when activity coefficients are considered. The 5% concentration by weight is less concentrated than 5 M HCl, so its pH would be higher (less negative) than -1.1, but a precise value requires the density of the 5% HCl solution to determine its molarity.".
AI-generated answer. Please verify critical facts.
HCl to pH Conversion
"The pH of a 5% hydrochloric acid (HCl) solution cannot be directly calculated from the percentage concentration without knowing the specific density of the solution to convert it to molarity. However, the pH of a 5 M HCl solution, which is a common reference point for concentrated HCl, is approximately -0.69 when calculated using the standard formula \mathrm{pH} = -\log[\ce{H3O+}], assuming complete dissociation of the strong acid. This calculation assumes the concentration of hydronium ions [\ce{H3O+}] is equal to the molar concentration of HCl.
It is important to note that for such a high concentration, the actual pH is influenced by the activity of the ions rather than just their concentration, and the true pH is likely lower than -0.69 due to non-ideal behavior. For a 5 M HCl solution, the pH is estimated to be around -1.1 when activity coefficients are considered. The 5% concentration by weight is less concentrated than 5 M HCl, so its pH would be higher (less negative) than -1.1, but a precise value requires the density of the 5% HCl solution to determine its molarity.".
AI-generated answer. Please verify critical facts.
Last edit: 25 Aug 2025 02:18 by CLO2.
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